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trans-1,3-dithiane-1,3-dioxide; a chiral acyl anion equivalent. Enantioselective synthesis of -hydroxy- carboxylic acids, esters, amides and ketones  • ARTICLEVarinder K. Aggarwal, Abraham Thomas and Steffen Schade Abstract | Abstract + References | PDF (952 K) | |||
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Catalytic enantioselective allylic oxidation of olefins with copper(I) catalysts and new perester oxidants  • ARTICLE Merritt B. Andrus and Xi Chen Abstract | Abstract + References | PDF (480 K) | |||
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Ring expansion by in situ tethering of hydroxy azides to ketones: The boyer reaction  • ARTICLE Vijaya Gracias, Kristine E. Frank, Gregory L. Milligan and Jeffrey Aubé Abstract | Abstract + References | PDF (797 K) | |||
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Enantioselective allene/enone photocycloadditions: The use of an inexpensive optically active 1,3-disubstituted allene  • ARTICLE Mary S. Shepard and Erick M. Carreira Abstract | Abstract + References | PDF (1443 K) | |||
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Application of the chemo- and enantioselective cyclopropanation of polyenes to the total synthesis of (+)-bicyclohumulenone  • ARTICLE AndréB. Charette and Hélène Juteau Abstract | Abstract + References | PDF (512 K) | |||
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Stereoselective total synthesis of (+)-lactacystin from Noritaka Chida, Jun Takeoka, Kohji Ando, Noriko Tsutsumi and Seiichiro Ogawa Abstract | Abstract + References | PDF (775 K) | |||
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A remarkable ene-like reaction: Development and synthetic applications  • ARTICLE Marco A. Ciufolini, Melissa V. Deaton, Shuren Zhu and Mingying Chen Abstract | Abstract + References | PDF (973 K) | |||
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The development of strategies for construction of the aziridine core of the antitumor agents azinomycins A and B  • ARTICLE Robert S. Coleman and Andrew J. Carpenter Abstract | Abstract + References | PDF (779 K) | |||
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Chiral auxiliary mediated pictet-spengler reactions: Asymmetric syntheses of (−)-laudanosine, (+)-glaucine and (−)-xylopinine  • ARTICLE Daniel L. Comins, Paresh M. Thakker, Matthew F. Baevsky and Mohamed M. Badawi Abstract | Abstract + References | PDF (587 K) | |||
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Complementary regioselective cyclopropyl ring openings of 6-formyl-spirobicyclo[5.2]octane mediated by TMSCl and TBAI  • ARTICLE He Huang and Craig J. Forsyth Abstract | Abstract + References | PDF (395 K) | |||
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A mild, convenient, and inexpensive method for converting imines into amines: Tin-catalyzed reduction with polymethylhydrosiloxane (PMHS)  • ARTICLE Rosa M. Lopez and Gregory C. Fu Abstract | Abstract + References | PDF (338 K) | |||
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Studies on the synthesis of C-Glycoside sulfones as potential glycosyl transferase inhibitors  • ARTICLE Jacquelyn Gervay, Terrence M. Flaherty and Daniel Holmes Abstract | Abstract + References | PDF (505 K) | |||
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The synthesis and reactions of some novel pyranoid 5,6-glycals derived from D-fructose  • ARTICLE Karl J. Hale, Soraya Manaviazar and Rukpong Tupprasoot Abstract | Abstract + References | PDF (762 K) | |||
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Synthesis of amino sugars through a highly diastereoselective dipolar cycloaddition. Enantioselective synthesis of the carbohydrate segment of Sch 38516  • ARTICLE Zhongmin Xu, Charles W. Johannes, Daniel S. La, Gloria E. Hofilena and Amir H. Hoveyda Abstract | Abstract + References | PDF (735 K) | |||
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Synthesis of sulfated trisaccharide ligands for the selectins  • ARTICLE William J. Sanders, David D. Manning, Kathryn M. Koeller and Laura L. Kiessling Abstract | Abstract + References | PDF (2274 K) | |||
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The asymmetric Baylis-Hillman reaction as a template in organic synthesis  • ARTICLE Linda Joy Brzezinski, Sara Rafel and James W. Leahy Abstract | Abstract + References | PDF (717 K) | |||
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Sequential application of stereoselective syn-oxidation methodologies to natural product synthesis: A potentially biomimetic approach to the C12–C21 bistetrahydrofuran region of monensin  • ARTICLE Frank E. McDonald and Colleen C. Schultz Abstract | Abstract + References | PDF (820 K) | |||
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Nickel-catalyzed heterocycle construction with stereoselective exocyclic alkene introduction  • ARTICLE John Montgomery, Maxim V. Chevliakov and Harry L. Brielmann Abstract | Abstract + References | PDF (758 K) | |||
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A new synthesis of -arylglycines from aryl boronic acids  • ARTICLENicos A. Petasis, Andrew Goodman and Ilia A. Zavialov Abstract | Abstract + References | PDF (413 K) | |||
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Studies of the tandem Mukaiyama aldol-lactonization (TMAL) reaction: A concise and highly diastereoselective route to -lactones applied to the total synthesis of the potent pancreatic lipase inhibitor, (−)-Panclicin D  • ARTICLEHong Woon Yang, Cunxiang Zhao and Daniel Romo Abstract | Abstract + References | PDF (1124 K) | |||
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Tandem radical nitrile transfer-cyclization reactions of 1,3-dioxane-4-nitriles: Synthesis of spirocyclic systems  • ARTICLE Scott D. Rychnovsky and Sonja S. Swenson Abstract | Abstract + References | PDF (886 K) | |||
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New chiral ligands for the asymmetric copper catalyzed conjugate addition of Grignard reagents to enones  • ARTICLE Eric L. Stangeland and Tarek Sammakia Abstract | Abstract + References | PDF (468 K) | |||
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Selectivity in ring-opening metatheses  • ARTICLE John A. Tallarico, Michele L. Randall and Marc L. Snapper Abstract | Abstract + References | PDF (596 K) | |||
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Asymmetric approaches to 1,2-disubstituted mitosenes based on the intramolecular cyclization of diazoesters  • ARTICLE Sangku Lee, Hee-Jong Lim, Kobpurn Lulu Cha and Gary A. Sulikowski Abstract | Abstract + References | PDF (744 K) | |||
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C-Glycosyl juglone in angucycline synthesis: Total synthesis of galtamycinone, common aglycon of C-glycosyl naphthacenequinone-type angucyclines  • ARTICLE Takashi Matsumoto, Hiroki Yamaguchi and Keisuke Suzuki Abstract | Abstract + References | PDF (822 K) | |||
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A new chiral titanium species for the ring opening reactions of meso epoxides  • ARTICLE Alecia W. Eppley and Nancy I. Totah Abstract | Abstract + References | PDF (534 K) | |||
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Cyclizations of unsymmetrical bis-1,2-(3-indolyl)ethanes: Synthesis of (−)-tjipanazole F1  • ARTICLE Eric J. Gilbert, Joseph W. Ziller and David L. Van Vranken Abstract | Abstract + References | PDF (691 K) | |||
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A short, enantioselective synthesis of (−)-epilupinine from proline via a spirocyclic ammonium ylide  • ARTICLE B. N. Naidu and F. G. West Abstract | Abstract + References | PDF (599 K) | |||
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Zirconocene-catalyzed epoxy ester - ortho ester rearrangement: A new method for the protection of polyfunctionalized carboxylic acids and the asymmetric synthesis of ortho esters  • ARTICLE Peter Wipf, Wenjing Xu, Hongyong Kim and Hidenori Takahashi Abstract | Abstract + References | PDF (1365 K) | |||
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Preparation and synthetic utility of oxasilacyclopentane acetals derived from siliranes  • ARTICLE Jared T. Shaw and K. A. Woerpel Abstract | Abstract + References | PDF (621 K) | |||
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Preface  • EDITORIAL John L. Wood Abstract | Abstract + References | PDF (70 K) | |||
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Contributors to this issue  • MISCELLANEOUS PDF (36 K) | |||
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Tetrahedron Symposia-in-Print  • ANNOUNCEMENT PDF (185 K) | |||
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Graphical abstracts  • ABSTRACT PDF (370 K) | |||